Showing posts with label Evolution of Chemistry. Show all posts
Showing posts with label Evolution of Chemistry. Show all posts

Friday, December 29

Supercapacitors: The Future of Energy Storage

 Introduction: 

Supercapacitors have found their way into our daily lives, revolutionizing various aspects of modern living. In our smartphones and portable electronic devices, supercapacitors enable rapid charging, allowing us to power up our devices quickly and efficiently. They also play a crucial role in electric vehicles, providing the necessary power for acceleration and regenerative braking, enhancing energy efficiency and reducing carbon emissions. In renewable energy systems, supercapacitors store excess energy generated from sources like solar and wind, ensuring a stable and reliable power supply. Additionally, supercapacitors are used in power backup systems, ensuring uninterrupted operation during power outages, and in wearable devices, providing extended battery life and quick charging capabilities. With their versatility, high power density, and long cycle life, supercapacitors have become an integral part of our daily lives, enhancing our energy storage and power delivery needs.


In today's world, where energy demands are increasing and the need for clean and sustainable energy sources is paramount, researchers and scientists are constantly exploring new technologies to meet these challenges. One such technology that has gained significant attention is the supercapacitor. Supercapacitors, also known as ultracapacitors or electrochemical capacitors, offer a promising solution for energy storage with their high power density, long cycle life, and rapid charge-discharge capabilities. In this blog post, we will delve into the world of supercapacitors, exploring their working principles, advantages, applications, and future developments.

Understanding Supercapacitors: 

Supercapacitors are energy storage devices that bridge the gap between traditional capacitors and batteries. Unlike batteries, which store energy through chemical reactions, supercapacitors store energy electrostatically. They consist of two electrodes separated by an electrolyte, and the energy is stored in the form of electrical charges at the electrode-electrolyte interface. This mechanism allows supercapacitors to deliver high power outputs and have a longer cycle life compared to batteries.

Advantages of Supercapacitors:

  1. High Power Density: Supercapacitors can deliver and absorb energy rapidly, making them ideal for applications that require quick bursts of power, such as electric vehicles and regenerative braking systems.
  2. Long Cycle Life: Supercapacitors can withstand hundreds of thousands of charge-discharge cycles without significant degradation, ensuring their longevity and reliability.
  3. Rapid Charging: Supercapacitors can be charged in a matter of seconds or minutes, making them highly suitable for applications that require fast energy storage and retrieval.
  4. Wide Temperature Range: Supercapacitors can operate efficiently over a wide temperature range, making them suitable for extreme environments.
  5. Environmentally Friendly: Supercapacitors do not contain toxic materials like some batteries, making them more environmentally friendly and easier to recycle.

Applications of Supercapacitors:

  1. Electric Vehicles (EVs): Supercapacitors play a crucial role in EVs by providing the necessary power for acceleration and regenerative braking, enhancing overall energy efficiency.
  2. Renewable Energy Integration: Supercapacitors can store excess energy generated from renewable sources like solar and wind, allowing for a more stable and reliable power supply.
  3. Consumer Electronics: Supercapacitors are used in smartphones, laptops, and wearable devices to provide quick charging capabilities and extend battery life.
  4. Power Backup Systems: Supercapacitors can be used as backup power sources in case of power outages, ensuring uninterrupted operation in critical applications.
  5. Aerospace and Defense: Supercapacitors are used in aerospace and defense applications, such as powering satellites, providing backup power for critical systems, and enhancing the performance of unmanned aerial vehicles (UAVs).

Future Developments: 

Researchers are continuously exploring ways to improve the energy density of supercapacitors to make them more competitive with traditional batteries. This includes developing new electrode materials, such as graphene and carbon nanotubes, and exploring advanced electrolytes and hybrid systems. Additionally, advancements in nanotechnology and manufacturing techniques are expected to further enhance the performance and reduce the cost of supercapacitors, making them more accessible for widespread adoption.


Conclusion: 

Supercapacitors have emerged as a promising technology for energy storage, offering high power density, long cycle life, and rapid charging capabilities. With their numerous advantages and diverse applications, supercapacitors are poised to revolutionize the energy storage landscape. As research and development in this field continue to progress, we can expect to see even more efficient and cost-effective supercapacitors in the near future. With their potential to transform various industries and contribute to a greener and more sustainable future, supercapacitors are undoubtedly a key player in the energy storage revolution.


References:

1. Jiang, W., et al., Hollow-tubular porous carbon derived from cotton with high productivity for enhanced performance supercapacitor. Journal of Power Sources, 2019. 438.

2. Bi, Z., et al., Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review. Journal of Materials Chemistry A, 2019. 7(27): p. 16028-16045.

3. Senthil, C. and C.W. Lee, Biomass-derived biochar materials as sustainable energy sources for electrochemical energy storage devices. Renewable and Sustainable Energy Reviews, 2021. 137.

4. Zhu, Z. and Z. Xu, The rational design of biomass-derived carbon materials towards next-generation energy storage: A review. Renewable and Sustainable Energy Reviews, 2020. 134.

5. Li, S., et al., Pore Structure Regulation and Electrochemical Performance Characterization of Activated Carbon for Supercapacitors. Frontiers in Energy Research, 2021. 9.

6. Tan, Z., et al., The changing structure by component: Biomass-based porous carbon for high-performance supercapacitors. J Colloid Interface Sci, 2021. 585: p. 778-786.

7. Rawat, S., R.K. Mishra, and T. Bhaskar, Biomass derived functional carbon materials for supercapacitor applications. Chemosphere, 2022. 286(Pt 3): p. 131961.

8. Yan, D., et al., Biomass‐Derived Activated Carbon Nanoarchitectonics with Hibiscus Flowers for High‐Performance Supercapacitor Electrode Applications. Chemical Engineering & Technology, 2022. 45(4): p. 649-657.

9. Yu, L. and G.Z. Chen, Ionic Liquid-Based Electrolytes for Supercapacitor and Supercapattery. Front Chem, 2019. 7: p. 272.

10. Gao, Z., et al., Biomass-derived renewable carbon materials for electrochemical energy storage. Materials Research Letters, 2016. 5(2): p. 69-88.

11. Barker, M. The Mechanism of Charcoal Activation. Ind. Eng. Chem. 1930, 22, 926–931.

12. Olivares-Marín, M.; Fernández, J.A.; Lázaro, M.J.; Fernández-González, C.; Macías-García, A.; Gómez-Serrano, V.; Stoeckli, F.; Centeno, T.A. Cherry Stones as Precursor of Activated Carbons for Supercapacitors. Mater. Chem. Phys. 2009, 114, 323–327.

13. Karnan, M.; Subramani, K.; Sudhan, N.; Ilayaraja, N.; Sathish, M. Aloe Vera Derived Activated High-Surface-Area Carbon for Flexible and High-Energy Supercapacitors. ACS Appl. Mater. Interfaces 2016, 8, 35191–35202.

14. Yadav, N., et al., Hierarchical porous carbon derived from eucalyptus-bark as a sustainable electrode for high-performance solid-state supercapacitors. Sustainable Energy & Fuels, 2020. 4(4): p. 1730-1746.


15. Chowdhury, Z.Z.; Zain, S.M.; Khan, R.A.; Islam, M. Preparation and Characterizations of Activated Carbon from Kenaf Fiber for Equilibrium Adsorption Studies of Copper from Wastewater. Korean J. Chem. Eng. 2012, 29, 1187–1195.


Monday, March 20

Organic Chemistry Past to Future


Organic chemistry is the study of the properties, structure, composition, and reactions of organic compounds, which are compounds that contain carbon atoms. Organic chemistry has a rich and fascinating history, and has played a significant role in the development of modern science and technology. In this blog post, we will take a journey through the history of organic chemistry, from its origins in ancient times to its current state and future prospects.

The Origins of Organic Chemistry

The study of organic compounds can be traced back to ancient times, where natural substances such as plants, animals, and minerals were used for medicinal purposes. However, the systematic study of organic compounds did not begin until the 19th century, when chemists began to investigate the properties of carbon-containing compounds.

In 1828, Friedrich Wöhler synthesized urea, an organic compound, from inorganic substances, proving that organic compounds could be made synthetically. This discovery challenged the prevailing belief that organic compounds could only be produced by living organisms.

The Golden Age of Organic Chemistry

The 19th century was a golden age of organic chemistry, marked by many important discoveries and breakthroughs. In 1858, Friedrich Kekulé proposed the concept of the benzene ring, which became the basis for the study of aromatic compounds.

In the early 20th century, chemists began to investigate the structure and properties of macromolecules, such as proteins and carbohydrates. This led to the discovery of many important biomolecules, such as DNA and enzymes.

During this time, chemists also began to develop new synthetic methods for the production of organic compounds. One of the most important of these was the Grignard reaction, discovered by Victor Grignard in 1900, which is still widely used in organic synthesis today.

The Rise of Biochemistry

In the mid-20th century, organic chemistry became increasingly intertwined with the study of biochemistry. Biochemistry, which is the study of the chemical reactions that take place within living things, significantly draws from the concepts of organic chemistry.

One of the most important discoveries in biochemistry was the structure of DNA, which was elucidated by James Watson and Francis Crick in 1953. This discovery revolutionized the field of molecular biology and paved the way for the development of genetic engineering and biotechnology.

The Future of Organic Chemistry

Today, organic chemistry continues to play a vital role in the development of new materials, drugs, and technologies. Chemists are continually discovering new methods for the synthesis of complex organic compounds, as well as developing new techniques for the analysis and characterization of these compounds. One of the most exciting areas of research in organic chemistry is the development of new materials with novel properties. For example, researchers are working on the development of new polymers with improved mechanical and electrical properties, as well as new materials for use in energy storage and conversion. Another area of research is the development of new drugs and therapies. Organic chemistry is essential for the discovery and synthesis of new drugs, as well as for the study of the mechanisms by which these drugs act in the body.

In the future, it is likely that organic chemistry will continue to be a vital and rapidly evolving field, with new discoveries and breakthroughs constantly pushing the boundaries of what is possible. From the origins of organic chemistry in ancient times to the present day and beyond, the journey of organic chemistry is a fascinating and inspiring one that continues to shape the world we live in today.

Sunday, March 19

Chemistry Involved About Burger

 It's possible that you may not consider the chemistry involved in creating a juicy burger until you take a bite. Yet, the chemistry of hamburgers is actually a fascinating and intricate subject that involves a variety of chemical interactions.

The burger

The patty, which is commonly produced from ground beef, is the foundation of every burger. Proteins, lipids, and amino acids are just a few of the chemical compounds found in beef that give it flavor, texture, and nutritional value. These molecules undergo a number of chemical interactions throughout the cooking process of the beef, creating new chemicals. The Maillard process, which happens when the beef's amino acids and sugars interact, is one of the most significant reactions.

A number of intricate chemical processes take place during the Maillard reaction, creating new chemicals that give the burger its distinct flavor and scent. The burger's rich, savory flavor comes from a range of volatile chemical compounds, including aldehydes, ketones, and pyrazines.

The bun

Another significant burger ingredient is the bun, which also contains a range of organic compounds that enhance the burger's flavor and texture. The flour used to make the bun is typically wheat, which has a wide range of proteins, starches, and other ingredients.

These chemicals undergo a number of chemical reactions during baking that result in the creation of new molecules. The Maillard process, which takes place when the wheat flour's sugars and amino acids interact, is one of the most significant reactions.

Aldehydes, ketones, and pyrazines are only a few of the volatile organic substances that are created during the Maillard reaction and give the bun its distinct flavor and aroma. The bun's texture is also crucial, and this is partly because of the gluten included in wheat flour. The complex protein gluten gives the bun its elasticity and aids in its shape retention.

The garnishes

A burger's toppings might come in a vast variety, but they all contain different organic molecules that add to the burger's overall flavor and texture. For instance, cheese has a distinct flavor and texture because it contains a range of lipids, proteins, and other substances.

A number of chemical processes take place when the cheese is melted on top of the patty, changing these molecules into new ones. The caramelization of the lactose in the cheese is one of the most significant processes because it produces a number of volatile organic compounds that give the cheese its savory, rich flavor.

Comparable organic compounds, including vitamins, minerals, and antioxidants, are present in vegetables like lettuce and tomato, adding to the burger's nutritional worth. Particularly when they are fresh and ripe, these molecules can also contribute to the flavor and texture of the burger.

The condiments

Finally, the condiments on a burger can also contain a variety of organic molecules that contribute to the overall flavor and texture of the burger. Ketchup, for example, contains a variety of sugars, acids, and other compounds that give it its sweet, tangy taste.

When the ketchup is applied to the burger, a variety of chemical reactions occur that transform these compounds into new compounds. One of the most important reactions is the caramelization of the sugars present in the ketchup, which results in the formation of a variety of volatile organic compounds that give it its characteristic flavor and aroma.

Similarly, mustard contains a variety of volatile organic compounds, such as isothiocyanates and sulfoxides, that give it its pungent taste and aroma. These compounds are formed when the mustard seeds are ground and mixed with vinegar, which causes a variety of chemical reactions to occur.

The chemistry of burgers is a complex and fascinating topic that involves a wide range of chemical reactions. From the Maillard reaction that occurs during the cooking of the patty and bun, to the formation of new compounds in the toppings and condiments, every element of a burger has its own unique chemistry that contributes to its overall flavor and texture.

While the chemistry of burgers is certainly interesting from an academic perspective, it also has practical implications. For example, understanding the chemical reactions that occur during cooking can help chefs to create burgers that are more flavorful and appealing to the palate. Similarly, understanding the chemical composition of different ingredients can help food manufacturers to develop new and innovative products that meet the changing tastes and preferences of consumers.

However, it's also important to note that while the chemistry of burgers is fascinating, it's only one piece of the puzzle when it comes to understanding the broader impact of our food choices. From the environmental impact of beef production, to the health implications of consuming large amounts of red meat, there are many factors to consider when it comes to making informed and responsible food choices.
In conclusion, the chemistry of burgers is a fascinating and complex topic that highlights the intricate relationship between food, science, and culture. While it's easy to take a simple pleasure like biting into a juicy burger for granted, understanding the chemistry that goes into making it can help us to appreciate the complexity and beauty of the world around us.

Saturday, March 18

Chemistry of Gasoline

 The fossil fuel known as crude oil, which was created over millions of years from the remains of ancient sea animals, is the main ingredient of gasoline, commonly referred to as petrol. It is a complicated blend of chemicals that improve its performance as well as organic molecules made of hydrogen and carbon atoms and hydrocarbons.

Depending on where it comes from, gasoline's chemical makeup can change, although it normally consists of a blend of cyclic hydrocarbons, straight-chain hydrocarbons, and branched-chain hydrocarbons. Octane (C8H18), a straight-chain hydrocarbon having eight carbon atoms and 18 hydrogen atoms, is the most prevalent hydrocarbon in gasoline.

In an internal combustion engine, burning gasoline causes a series of chemical processes that result in the production of energy in the form of heat and motion. The following equation can be used to model how gasoline burns:

C8H18 + 12.5O2 -> 8CO2 + 9H2O + heat

Octane and oxygen interact in this reaction to create carbon dioxide, water, and heat. The engine of a car is propelled by the heat energy created when gasoline burns, which moves the wheels.

The octane rating of gasoline, which is a gauge of its capacity to withstand knocking or pinging during combustion, determines how effective it is as a fuel. When the fuel-air mixture in an engine cylinder ignites too soon, it can cause knocking. This sudden increase in pressure can harm the engine. Because high-octane gasoline less frequently results in knocking, engines may run at higher compression ratios and generate greater power.

Together with hydrocarbons, gasoline also has a number of additives that improve its functionality and safeguard the engine. Detergents, which assist keep the fuel injectors and intake valves clean and stop deposits from accumulating, are one of the most crucial additions in gasoline. Additional additions include corrosion inhibitors, which shield the engine from rust and other types of corrosion, and antioxidants, which stop the fuel from oxidizing and producing dangerous substances.


The refining process

The production of gasoline begins with the refining of crude oil, a process that involves separating the various components of the oil by their boiling points. Crude oil is heated in a distillation tower, which causes the lighter, more volatile components to vaporize and rise to the top, where they are condensed and collected.

The initial distillation of crude oil yields a mixture of hydrocarbons called naphtha, which is then further processed to produce gasoline. The naphtha is first treated with hydrogen to remove impurities and increase its octane rating. It is then subjected to a process called catalytic cracking, which breaks the large hydrocarbon molecules into smaller ones that are more useful as gasoline.

The resulting gasoline is then blended with various additives to improve its performance and protect the engine. The composition of the additives can vary depending on the intended use of the gasoline. For example, gasoline used in colder climates may contain more volatile components to improve cold-start performance, while gasoline used in high-altitude areas may contain less oxygen to compensate for the lower air pressure.

Environmental impact

While gasoline is an important fuel for transportation and other applications, its production and use have significant environmental impacts. The combustion of gasoline produces carbon dioxide, a greenhouse gas that contributes to climate change, as well as other harmful pollutants such as nitrogen oxides and particulate matter.

In addition to the emissions produced during combustion, the production of gasoline also generates significant amounts of greenhouse gases and other pollutants. The refining process consumes large amounts of energy and produces emissions of carbon dioxide and other greenhouse gases, as well as various air pollutants.

To address these environmental impacts, efforts are underway to develop alternative fuels and improve the efficiency of gasoline-powered vehicles. Biofuels, such as ethanol and biodiesel, can be produced from renewable sources such as crops and waste materials, and they have the potential to reduce greenhouse gas emissions and other pollutants. Hybrid and electric vehicles are also becoming increasingly popular as they produce little to no emissions during operation, although the production of the electricity used to power these vehicles can still have environmental impacts.

In addition to alternative fuels and vehicle technologies, there are also efforts underway to improve the efficiency of gasoline engines. Advances in engine design, such as direct injection and turbocharging, can increase fuel efficiency and reduce emissions. Additionally, efforts are being made to develop more efficient and environmentally friendly refining processes, such as using renewable energy sources and reducing waste and emissions.


Lastly, Gasoline is a complex mixture of hydrocarbons and additives that is an important fuel for transportation and other applications. The chemical composition of gasoline can vary depending on its source, and its efficiency as a fuel depends on its octane rating. While gasoline is a widely used and convenient fuel, its production and use have significant environmental impacts, including greenhouse gas emissions and air pollution. Efforts are underway to develop alternative fuels and improve the efficiency of gasoline-powered vehicles, as well as to reduce the environmental impact of the refining process.

Monday, February 6

Some Great Chemists of All Time

There have been many outstanding chemists who have contributed significantly to the field of chemistry throughout history. The most prominent ones are as follows:

1. Lavoisier, Antoine (1743-1794)

The founder of contemporary chemistry is regarded as Antoine Lavoisier. He was a French aristocrat and chemist who transformed the discipline by introducing the idea of mass conservation and carrying out methodical experiments to establish the law of mass conservation. He also identified numerous elements, including sulfur and phosphorus, and established the function of oxygen in respiration and combustion. Modern chemistry was established by Lavoisier's work, and his achievements are still honored and researched today. 

2. Robert Boyle (1627-1691)

Irish scientist and physicist Robert Boyle is renowned for his studies on the characteristics of gases. Boyle's law, which asserts that the pressure and volume of a gas are inversely related as long as the temperature doesn't change, is his most famous contribution. Boyle's work opened the door for contemporary chemistry as well as thermodynamics research in the future. He was also one of the first to understand the value of experimentation in scientific research and published a great deal about the process of conducting experiments in science.

3. John Dalton (1766-1844)

The atomic theory of matter was created by English chemist and scientist John Dalton. He suggested that all substance is composed of indestructible, indivisible atoms. Along with that, he created the concept of atomic weights and calculated the relative atomic weights of various elements. Dalton's contributions were crucial in turning chemistry into a quantitative discipline, and his atomic theory remains a pillar of contemporary chemistry.

4. Dmitri Mendeleev (1834-1907)

Russian chemist Dmitri Mendeleev is credited with creating the periodic table of elements. He observed that elements with comparable chemical and physical properties appeared in the same column of the table when he sorted the elements in order of increasing atomic weight. The periodic law and the behavior of elements in chemical reactions were first understood through the work of this author. One of the most significant contributions to the science of chemistry, Mendeleev's periodic table is still in use today.

5. Marie Curie (1867-1934)

Polish-born scientist and physicist Marie Curie made significant advances in the study of radioactivity and nuclear physics. She was the first person to win two Nobel Prizes in distinct fields and the first woman to earn a Nobel Prize. Curie was one of the pioneers in research into how radiation affects the human body and had a key role in the discovery of the elements polonium and radium. Her contributions made it possible for nuclear medicine to emerge and for radiation therapy to be used in the treatment of cancer.

6. Pauling, Linus (1901-1994)

American chemist Linus Pauling made significant contributions to quantum mechanics and molecular biology. With his 1954 Nobel Prize in Chemistry and 1962 Nobel Peace Prize, he became the first person to ever win two separate Nobel Prizes. Pauling made significant contributions to the understanding of the chemical bond and played a key role in the creation of quantum mechanics. Additionally, he contributed to the development of the area of molecular biology by discovering the structure of proteins.

7. Carl Sagan (1934-1996)

American astronomer and chemist Carl Sagan made significant contributions to planetary science and astrochemistry. He was an educator and popular science writer best known for his contribution to the popularization of science. Sagan made significant contributions to the area of astrochemistry and was crucial in its growth.

8. Alfred Nobel

Swedish chemist, engineer, and inventor Alfred Nobel is most known for establishing the Nobel Prizes. Over 350 patents were held by this famous merchant and entrepreneur who was born in Stockholm in 1833. Dynamite, a potent explosive material created by Alfred Nobel in 1867, completely changed the mining and building industries. Nobel was concerned about the destructive potential of dynamite in battle and other violent situations despite its usefulness. This inspired him to create the Nobel Prizes in 1895, which are given annually to people and organizations for their major achievements in the fields of economics, literature, physics, and chemistry. One of the most distinguished honors in the world, the Nobel Prizes are widely regarded as a mark of greatness and success. The prize presentation, which takes place every year in Stockholm, Sweden, is regarded as a significant worldwide occasion. The winners are chosen by panels of international experts, and the prizes come with a cash award and a diploma. The globe is still greatly impacted by Alfred Nobel's legacy even though he passed away in San Remo, Italy, in 1896. He wanted to honor people who had made significant contributions to society and to promote further scientific and technological advancement through the Nobel Prizes. His legacy continues to advance peace, science, and human achievement and has inspired millions of people worldwide.

9. Dorothy Crowfoot Hodgkin (1910–1994)

The British scientist Dorothy Crowfoot Hodgkin (1910–1994) made substantial contributions to the study of X-ray crystallography. She was raised in Cairo, Egypt, and attended the University of Oxford where she became interested in X-ray crystallography, a method for figuring out the three-dimensional structure of molecules. Hodgkin employed X-ray crystallography throughout her career to ascertain the structures of intricate biological compounds, such as penicillin, vitamin B12, and insulin. Her work set the path for future studies in the field of molecular biology and contributed to the recognition of X-ray crystallography as a crucial technique in the study of biological molecules. For her groundbreaking work in X-ray crystallography and her contribution to our understanding of the structure of living molecules, Hodgkin received the Nobel Prize in Chemistry in 1964. She is regarded as one of the top female scientists of the 20th century and was the third woman to win the Chemistry Nobel Prize. Along with her contributions to science, Hodgkin was a vocal supporter of world peace and human rights who used her platform to advance these causes. She was a strong opponent of the apartheid government in South Africa and a member of the Pugwash Conferences on Science and World Affairs, an organization devoted to lowering the possibility of nuclear war. The legacy of Hodgkin still motivates and shapes scientists and researchers everywhere. Her groundbreaking X-ray crystallography research has aided in the discovery of previously unknown properties of intricate biological molecules and deepened our understanding of the molecular basis of life. She continues to serve as an inspiration to people who want to change the world for the better and as a role model for young scientists.

10. Rosalind Franklin (1920-1958)

Rosalind Franklin, a British chemist and X-ray crystallographer who lived from 1920 to 1958, significantly influenced our understanding of the structure of DNA. She was raised in London and graduated from the University of Cambridge with a degree in physics before going on to conduct graduate studies in X-ray crystallography. James Watson and Francis Crick's 1953 publication of their discovery of the double helix structure of DNA owed much to Franklin's work in X-ray crystallography. She discovered the "B form" of DNA, which is distinguished by a regular pattern of repeating units, thanks to the X-ray diffraction photographs she took of DNA fibers. These photos also helped scientists better understand the structure of the molecule. However, during her lifetime, Franklin's contributions to the understanding of the structure of DNA were frequently disregarded and underappreciated. She did not win the Nobel Prize for her work, which was given to Watson, Crick, and Maurice Wilkins in 1962, nor did she receive any recognition for it. Despite this, Franklin's contributions to the study of molecular biology and genetics have had a lasting effect. She has become a role model for many scientists and a symbol of the difficulties experienced by women in the sciences thanks to her creative X-ray crystallography techniques and commitment to her work. Franklin's legacy has been honored even after she passed away at the age of 37 from ovarian cancer. She has received various honors, including the naming of the Rosalind Franklin Institute, a significant research center for the life sciences in the UK. She continues to serve as a source of inspiration for scientists and researchers all around the world and is a living example of the value of furthering knowledge and scientific research.

Wednesday, January 18

Research fields in chemistry

Chemistry is a constantly evolving field, with new discoveries and advancements being made on a regular basis. In this blog post, we will explore some of the most exciting and cutting-edge research currently taking place in the field of chemistry.


One area of chemistry that has seen significant developments in recent years is the field of materials science. Researchers are working to develop new materials with unique properties that can be used in a wide range of applications, from electronics and energy storage to biomedical devices and aerospace. One particularly promising area of research is the development of new types of superconductors, which are materials that can conduct electricity with 100% efficiency. These materials have the potential to revolutionize transportation and energy production, as they could enable the creation of more efficient and powerful electrical systems.


Another area of chemistry that is currently attracting a lot of attention is the field of organic chemistry. Organic chemists are working to design and synthesize new molecules and materials that can be used in a wide range of applications, from medicine to electronics. One particularly exciting area of research is the development of new drugs to treat a wide range of diseases, such as cancer and Alzheimer's. Researchers are also working to create new materials that can be used in electronic devices, such as OLEDs (organic light-emitting diodes) and solar cells.


Nanotechnology is also an area of chemistry that is seeing a lot of research activity. In this field, scientists are working to manipulate matter at the atomic and molecular level to create new materials with unique properties. These materials have the potential to be used in a wide range of applications, from medicine to electronics. One particularly promising area of research is the development of new types of nanocomposites, which are materials made up of tiny particles that are less than 100 nanometers in size. These materials have the potential to be used in a wide range of applications, from biomedical devices to energy storage.


Green chemistry is another field of research that is becoming increasingly important. In this field, researchers are working to develop new chemical processes that are less harmful to the environment. This can be achieved by using renewable resources, designing more efficient processes, or developing new catalysts that can speed up reactions. One particularly promising area of research is the development of new types of biofuels, which can be used as an alternative to fossil fuels.


Lastly, research in computational chemistry is also becoming increasingly important. In this field, researchers use computer simulations to understand the behavior of molecules and materials. This has the potential to revolutionize the field of chemistry, by allowing scientists to predict the properties of new materials before they are even synthesized.


In conclusion, chemistry is a constantly evolving field with new discoveries and advancements being made on a regular basis. From materials science to organic chemistry, nanotechnology, green chemistry, and computational chemistry, researchers are making progress in areas that have the potential to revolutionize a wide range of industries, from transportation to medicine and energy production.




Friday, October 14

Chemistry of Fire

The chemical chain reaction which takes place with the evolution of heat and light is simply known as fire. Fire is an exothermic, self-sustaining chemical reaction that involves a solid, liquid, or gas-phase fuel and is typically associated with the oxidation of this fuel by atmospheric oxygen, which results in the emission of energy in the form of heat and light. In other words, a fuel and oxygen undergo a chemical reaction known as combustion that produces carbon dioxide and water. It is an exothermic reaction, which means that it generates heat. This is because the oxygen molecule's chemical connections are relatively weak, and the new bonds created are more stable, leading to a net production of energy.

Many of us had the basic combustion equation for fire drilled into us in school: fuel + oxygen = carbon dioxide + water. However, carbon dioxide is not produced in a direct chain during combustion events. As an alternative, numerous intermediary molecules are used throughout the way. These intermediate molecules can occasionally be created in extremely high amounts as a result of incomplete combustion. For instance, a flame that receives insufficient oxygen may create carbon monoxide rather than carbon dioxide.

When two gases react, creating both heat and light, a flame is created. Some flames burn hotter than others because different gases react in different ways and produce different quantities of energy. For example, a domestic candle's flame can burn at temperatures between 800 and 1000 degrees Celsius. By altering the reaction, for as by substituting pure oxygen for air, a flame can be made to burn at a greater temperature. Oxy-acetylene, which is created by burning a mixture of oxygen and acetylene, produces a flame that burns at over 3000°C and can be used to cut, melt, and weld metals.

Each stage of the process and all of the intermediate molecules involved, which naturally vary depending on the fuel, are still not entirely understood. This is one reason why we started studying fire in space; without the interference of gravity, it is simpler to investigate the more intricate aspects of combustion.

Conditions for a fire:

Oxygen in air As stated in the definition of fire, air oxygen is typically the oxidizing agent. The fact that oxygen makes up about 20% of the atmosphere, as will be detailed later, typically makes it simple to understand why it is actually present. The availability of oxygen, however, plays a crucial role in the intensity and spread of a fire.

Other oxidizing agents, such as potassium chlorate (KClO3) and sodium nitrate (NaNO3), which have oxygen in their chemical makeup, can provide oxygen to a fire under the right circumstances. Additionally, in extremely unusual circumstances, combustion can take place in an environment of carbon dioxide or another gas without oxygen.

Fuel Practically, any substance that exists in a chemical state where it may be oxidized by oxygen in the presence of a suitable ignition source can be regarded as the fuel mentioned in the definition.

In fire investigations, organic substances with considerable concentrations of carbon (often 50% and more) and hydrogen are the most frequent fuels that need to be taken into account. Natural substances like wood, cotton, and so on are among them, as are synthetic substances like plastics, paints, rubbers, and so forth, as well as refined fuels and solvents like gasoline, lighting kerosene, and methylated spirits.

Heat Energy is required to excite both the fuel and oxygen molecules to the active state essential for chemical reaction. The ignition temperature of the fuel is the lowest temperature required to start the "self-sustaining chemical reaction" mentioned in the definition of fire. Fire investigators are primarily interested in the source of ignition because this can be used to determine the cause of the fire.

Thursday, October 13

Chemistry Behind Colors

 When you think about it, color is kind of strange. Think about the different colors that you see around you every day. Each one of them has its own distinct properties, and yet they all seem to share some basic similarities. There are lots of different types of colors, but they are all variations of three primary colors: red, yellow, and blue. Red, yellow, and blue are also known as the primary colors because these three types of light can combine to create any other color on the spectrum.

 The result is a series of blue-green color combinations, the most common being red, yellow and green. All together these are usually referred to as 'red' or 'violet'.

It's not just about making it easier for people who want to buy organic cosmetics but more importantly because they could also benefit from this process – allowing them greater control over when their own skin gets affected by environmental pollution (including pesticides). "Most beauty products carry chemicals which make that happen," explains Professor Simon Morris, director general at British Cosmetics Association. Some have active ingredients such an insect repellent spray; others contain tiny amounts in soaps.

 These three (Red, yellow, and blue) hues are also the simplest to identify in a visual test because almost everyone can identify them as being one of those three hues. So what makes these specific colors so special? Let’s find out!

1. Blue

Blue color comes from the chemical structure of indigo. Indigo is a blue-colored dye extracted from plants of the genus Indigofera. It is produced by the oxidation of indole (a derivative of tryptamine) to indoxyl sulfate.

2. Green

 Green color comes from the chemical structures of chlorophyll and carotene. Chlorophyll is a green pigment present in all plants. Carotene is a yellowish orange pigment found in carrots and some fruits and vegetables.

3. Red

 Red color comes from the chemical compounds of anthocyanin. Anthocyanins are red pigments found in many flowers, berries, and roots.

4. Yellow

 Yellow color comes from the chemical compound of flavonoids. Flavonoids are yellow pigments found in many foods including apples, citrus fruits, onions, and chrysanthemums.

5. Orange

 Orange color comes from the chemical composition of lycopene. Lycopene is a reddish orange pigment found in tomatoes, watermelons, and guavas.

6. Purple

 Purple color comes from the chemical components of betalains. Betalains are purple pigments found in beetroot, amaranth, and pansies.

7. Brown

 Brown color comes from the chemical compositions of tannins. Tannins are brown colored pigments found in tea, wine, and oak trees.

Thursday, October 6

The Nobel Prize in Chemistry 2022: Click Chemistry

On 5 October 2022, The Royal Swedish Academy of Sciences has decided to award the Nobel Prize in Chemistry 2022 to Carolyn R. BertozziMorten Meldal and K. Barry Sharpless “for the development of click chemistry and bioorthogonal chemistry”.

 

In Click chemistry, the molecules are connected together with the simple command of "click." Making complicated processes simpler is the focus of the 2022 Nobel Prize in Chemistry. A functional branch of chemistry known as "click chemistry," in which molecular building pieces fit together rapidly and precisely, was established by Barry Sharpless and Morten Meldal. Click chemistry has been expanded by Carolyn Bertozzi, who has begun applying it to living things. For a very long time, chemists have been motivated by the ambition to create ever-more complex compounds. This has frequently involved generating artificial versions of natural compounds with therapeutic qualities in pharmaceutical research. This has produced numerous admirable molecular constructs, but they are typically time- and money-consuming to make.

The theme of this year's Chemistry Prize is working with what is straightforward and uncomplicated rather than overcomplicating things. Even by following a simple path, functional molecules can be created, according to Johan Qvist, Chair of the Nobel Committee for Chemistry. The initiative was established by Barry Sharpless, who is currently receiving his second Nobel Prize in Chemistry. He developed the idea of "click chemistry" around the year 2000, which is a type of straightforward chemistry in which reactions take place rapidly and unintended byproducts are avoided. Shortly after, independently of one another, Morten Meldal and Barry Sharpless presented the azide-alkyne cycloaddition, which is generally regarded as the pinnacle of click chemistry.
Now used frequently, this chemical reaction is both beautiful and effective. It is used, among many other things, to map DNA, produce medications, and make materials that are better suited for their intended application. 
Carolyn Bertozzi raised the bar for click chemistry. She created click reactions that function inside living beings in order to map crucial but elusive proteins called glycans that are found on the surface of cells. Her bioorthogonal processes happen without interfering with the cell's regular chemistry. Today, people all over the world employ these reactions to investigate cells and monitor biological processes. Researchers have enhanced the targeting of cancer medications using bioorthogonal processes, which are currently being examined in clinical studies.

Chemistry has entered the functionalism age thanks to click chemistry and bioorthogonal reactions. The greatest benefit to humanity is being provided by this. Illustrations Use of the illustrations for non-commercial uses is free. " Johan Jarnestad/The Royal Swedish Academy of Sciences" should be credited.

Illustrations

Illustration: Nobel prize in Chemistry



Illustration: The click reaction that changed chemistry 



Illustration: Bioorthogonal chemistry illuminates the cell


Brief Info about the Winners

Carolyn R. Bertozzi, born 1966 in USA. PhD 1993 from UC Berkeley, CA, USA. Anne T. and Robert M. Bass Professor at Stanford University, CA, USA.


Morten Meldal, born 1954 in Denmark. PhD 1986 from Technical University of Denmark, Lyngby, Denmark. Professor at University of Copenhagen, Denmark.


K. Barry Sharpless, born 1941 in Philadelphia, PA, USA. PhD 1968 from Stanford University, CA, USA. W. M. Keck Professor at Scripps Research, La Jolla, CA, USA.

 

Prize amount: 10 million Swedish kronor, to be shared equally between the Laureates.


Tuesday, September 27

The Chemistry Behind Your Phone: What You Need to Know

The average American checks their phone 150 times a week, and they don’t even have an iPhone. It’s not just the way we communicate that has changed; phones themselves are something very different from what they used to be. Smartphones today have many functions beyond making calls, sending texts, and checking email. In fact, most of us use our phones to take photos, stream music, access social media sites like Facebook and Instagram, play games, record video and much more. This article takes a look at all the amazing things your smartphone can do thanks to chemistry. We explore the role of science in your phone’s camera, microphone, speakers, battery and other features – along with how manufacturers achieve those results at an affordable price point – so you can geek out about it over happy hour with friends or family members.


The Camera: What’s Behind the Brightness, Colour and Resolution?

All of the major smartphone manufacturers use cameras made by a company called Sony. Those companies include Apple, Samsung, LG, Huawei, and even Google, which makes its own Pixel phones. Sony makes the sensors inside these cameras and the image processing software, too. Sony was an early pioneer in the use of these image sensors and the production of CMOS sensors. CMOS stands for complementary metal-oxide-semiconductor and it is used in most digital cameras today to capture and store an image, just like film in older cameras did. The sensors in these cameras get their brightness and colour by using an RGB filter, which is an approach that was introduced decades ago. The RGB colours represent the three primary colours needed to create the full spectrum of colour that our eyes can see. What makes these RGB filters special is that all three filters are made from a single piece of material. The colour filter is made from silicon, which is the main component in sand. The silicon is treated in different ways to produce either red, green or blue filters as needed.

Screen: How do they work?

The most important part of any smartphone is the screen. Without a screen, a phone isn’t much more than a brick. Fortunately, we have advanced technology that allows us to have large, bright screens in a tiny device. How do they work? A smartphone screen is made up of millions of tiny pixels. Each pixel is made up of two tiny red, green or blue light-emitting diodes (LEDs). When a pixel needs to be red, electricity travels through the LED and turns it on. This makes the pixel red. When electricity flows through the LED again, it turns off the pixel. This allows the pixel to be any colour in between red and black. The chemicals inside this LED are critical to its effectiveness. When electricity flows through the LED, it causes chemicals inside to travel between two electrodes. This releases photons (light particles) that are visible to the human eye. When the electricity stops flowing, the electrons go back to their original position, which stops the photons from being released. This process is repeated millions of times per second.

The Microphone: Why Are They So Good At Recording Audio?

Although audio is a secondary feature for most people when it comes to a smartphone, it’s still an important function for those who want to record concerts and sporting events, podcast, or even use the microphone as a voice-activated remote control for their TV. The primary mic in smartphones is usually the one used for answering and placing calls and it’s a basic MEMS or piezoelectric microphone. MEMS microphones have been around for decades and have very low noise compared to standard condenser microphones. They are also very small and they are used in smartphones, smart speakers, and almost all other audio devices, like Google Home, Amazon Echo, and Apple Homepod.


The Speakers: How Do They Sound So Good?

The speakers in smartphones are usually MEMS speakers, too, the same ones used in the microphones. Although smartphones have speakers on the front and back of the device, most people use the front speakers. That’s because the sound coming from the back speakers is reflected off of whatever surface the phone is resting on, creating a sound that is very muffled, and not nearly as loud as the sound from the front speaker. The speakers in a smartphone are both very tiny and very close together. It’s a design challenge that manufacturers work hard to overcome. Engineers use several different approaches to deal with this problem. One common technique is called “cascading,” where sound coming out of one speaker is used to drive the other speaker. Another approach is something called “acoustical coupling,” where the speakers are placed right next to each other so the sound is coupled together and travels through the air as one sound wave.


The Battery: Why Are Smartphone Batteries So Small?

While battery technology has evolved over the years, it hasn’t kept pace with the increase in power consumption of smartphones. The lithium-ion batteries used in smartphones are fairly recent. They have many advantages that have made them the battery of choice, including their light weight and ability to be recharged relatively easily. That said, lithium-ion batteries are not a perfect technology. They are still susceptible to catching fire if they are overcharged, used improperly, or are damaged in some way. All of the major smartphone manufacturers make their batteries in-house and have their own labs. In fact, many manufacturers have more than one lab because batteries are such a complicated part. It’s an incredibly difficult process to get the battery right and meet the standards set by international regulators. Each manufacturer has its own proprietary formula for the chemistry in its batteries, which is why they don’t all last the same amount of time.


Other Features: Fingerprint Scanners, Practice Software and More

Many smartphones have fingerprint scanners that are used for security and unlocking the phone, but they are also great for accessing certain apps. The fingerprint scanner that is used in Apple and Samsung phones is different than the fingerprint scanners that are used for authentication by law enforcement. It’s a capacitive sensor that uses a small electrical charge to determine if there’s a fingerprint there. Practice software can be installed on smartphones to help you improve your skills in many different areas. There are apps to help with foreign language skills, music skills, and even apps that help you practice mental exercises, like improving your memory or skills at critical thinking.


Final Thoughts

Phones have changed so much since the days of the rotary phone, but they are also very much the same, too. They are still a way for people to communicate with one another, they are just much faster, have better clarity and have the ability to go beyond just one conversation at a time. The phone has become so much more than that in today’s world, and it’s exciting to see what the future holds for them.

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